Paris Orly will be the latest new route from Berlin-Tegel for the carrier when it takes off in November.
Flights will run twice a day on weekdays and once a day at the weekend to complement the previously announced winter schedule.
Joachim Hunold, Chief Executive of Air Berlin, said: "This new route allows us to respond to the great demand for direct flights to Paris.
"The convenient departure times make this service particularly attractive for business travellers both from Germany and from France."
Air Berlin’s winter itinerary also includes flights to Athens, Gothenburg, Helsinki, Copenhagen and Zurich.
Flights to London and Manchester will also form part of the seasonal schedule with new services to Milan-Malpensa, Stockholm and Vienna also revealed.
Tickets are available to book now and the airline is offering cheap flights to passengers who book early.